Search results for "Bilayer films"

showing 2 items of 2 documents

Photocurrent spectroscopy in passivity studies

2018

The aim of this article is to present photocurrent spectroscopy as useful in situ technique for the physicochemical characterization of passive films and corrosion layers. The response of (both amorphous and crystalline) semiconductor/electrolyte junction under irradiation is treated and discussed in order to get information about solid-state properties such as band gap and flat band potential. The possibility to use Photocurrent Spectroscopy (PCS), in a quantitative way, to get information on the composition of corrosion layers is discussed through a semiempirical correlation between the band gap of the oxides (or hydroxides) and the difference of electronegativity of their constituents. F…

Materials scienceBand gapPassive film/electrolyte energetics02 engineering and technologyElectrolyte01 natural sciencesCorrosionElectronegativityPhotoelectrochemistryOptical band gap0103 physical sciencesSpectroscopy010302 applied physicsPhotocurrentBilayer filmsbusiness.industryCorrosion layersOxide layersAmorphous semiconductors021001 nanoscience & nanotechnologyAmorphous solidSemiconductorHydroxide layersSettore ING-IND/23 - Chimica Fisica ApplicataOptoelectronicsPassive films0210 nano-technologybusinessFlat band potential
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Surface, mechanical and barrier properties of bio-based composite films based on chitosan and whey protein

2014

Mono-component and composite bilayer and blend films composed of chitosan and whey protein were made. Colour, microstructure, water contact angles, swelling, water vapour sorption, barrier properties (oxygen, water vapour), water vapour diffusion coefficients and mechanical properties were determined. The influence of water vapour on barrier properties was studied in relation to the surface and structural properties. Mono-component and bilayer films were transparent with a homogeneous surface. Contrarily, blend films were translucent. Bilayer films had significantly lower water vapour permeability in comparison to mono-component and blend films. In all bilayer films, the air side (chitosan)…

Microbiology (medical)Whey proteinMaterials sciencePolymers and PlasticsBilayerComposite numbertechnology industry and agriculturefood and beveragesBilayer films ; Chitosan ; whey protein ; oxygen peremability ; surface properties ; microstructureMicrostructureBiomaterialsChitosanContact anglechemistry.chemical_compoundOxygen permeabilitychemistrymedicineSwellingmedicine.symptomComposite materialSafety Risk Reliability and QualityFood ScienceFood Packaging and Shelf Life
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